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Diethyl Ether vs. Propanol

What's the Difference?

Diethyl ether and propanol are both organic compounds commonly used as solvents. However, they have different chemical structures and properties. Diethyl ether is a volatile, highly flammable liquid with a sweet, ether-like odor, while propanol is a less volatile liquid with a stronger, more pungent odor. Diethyl ether is commonly used as a solvent in laboratories and as an anesthetic, while propanol is often used as a solvent in the production of pharmaceuticals and cosmetics. Overall, while both compounds have their own unique uses and characteristics, they serve as important solvents in various industries.

Comparison

AttributeDiethyl EtherPropanol
Chemical FormulaC4H10OC3H8O
Boiling Point (°C)34.697.2
Molar Mass (g/mol)74.1260.1
OdorSweet, pungentAlcohol-like
Solubility in WaterVery lowMiscible

Further Detail

Physical Properties

Diethyl ether, also known simply as ether, is a colorless, volatile liquid with a characteristic sweet odor. It has a boiling point of 34.6 degrees Celsius and a density of 0.713 grams per milliliter. In contrast, propanol is a colorless liquid with a strong odor. It has a boiling point of 97.2 degrees Celsius and a density of 0.804 grams per milliliter. While both substances are liquids at room temperature, propanol has a higher boiling point and density compared to diethyl ether.

Chemical Structure

Diethyl ether has the chemical formula C4H10O and consists of two ethyl groups attached to an oxygen atom. It is classified as an ether due to its functional group. Propanol, on the other hand, has the chemical formula C3H8O and consists of a propyl group attached to a hydroxyl group. Propanol is classified as an alcohol due to the presence of the hydroxyl group. The difference in chemical structure between diethyl ether and propanol contributes to their distinct properties and reactivity.

Solubility

Diethyl ether is slightly soluble in water, with a solubility of 6.9 g/L at 20 degrees Celsius. It is more soluble in organic solvents such as ethanol and acetone. Propanol, on the other hand, is miscible with water, meaning it can dissolve in any proportion. This difference in solubility is due to the presence of the hydroxyl group in propanol, which allows for hydrogen bonding with water molecules. Diethyl ether lacks this functional group, leading to lower solubility in water.

Flammability

Both diethyl ether and propanol are flammable substances. Diethyl ether has a flash point of -45 degrees Celsius, making it highly flammable. It can form explosive peroxides upon exposure to air and light. Propanol, on the other hand, has a flash point of 21 degrees Celsius, also indicating high flammability. While both substances pose a fire hazard, diethyl ether is known for its explosive potential due to the formation of peroxides over time.

Toxicity

Diethyl ether is considered to be a moderately toxic substance. It can cause irritation to the eyes, skin, and respiratory tract upon exposure. Prolonged or repeated exposure to diethyl ether may lead to central nervous system depression and other health effects. Propanol, on the other hand, is also toxic but to a lesser extent. It can cause irritation to the eyes, skin, and respiratory tract as well. However, propanol is less likely to cause central nervous system depression compared to diethyl ether.

Applications

Diethyl ether is commonly used as a solvent in chemical reactions and as a starting material for the synthesis of various compounds. It is also used as an anesthetic agent, although its use has declined due to safety concerns. Propanol is widely used as a solvent in the pharmaceutical and cosmetic industries. It is also used as a disinfectant and as a fuel additive. Both diethyl ether and propanol have important industrial applications, albeit in different sectors.

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