2-Methylpropan-2-ol vs. Iso Butanol
What's the Difference?
2-Methylpropan-2-ol and Iso Butanol are both alcohols with similar chemical structures, containing a branched carbon chain. However, 2-Methylpropan-2-ol, also known as tert-butanol, has a tertiary carbon atom bonded to three other carbon atoms, while Iso Butanol has a secondary carbon atom bonded to two other carbon atoms. This difference in carbon bonding affects their physical and chemical properties, with 2-Methylpropan-2-ol having a higher boiling point and lower solubility in water compared to Iso Butanol. Both alcohols are commonly used as solvents and in the production of various chemicals.
Comparison
Attribute | 2-Methylpropan-2-ol | Iso Butanol |
---|---|---|
Chemical Formula | C4H10O | C4H10O |
Molecular Weight | 74.12 g/mol | 74.12 g/mol |
Boiling Point | 82.5 °C | 107.9 °C |
Melting Point | -108 °C | -108 °C |
Density | 0.79 g/cm3 | 0.81 g/cm3 |
Further Detail
Chemical Structure
2-Methylpropan-2-ol, also known as tert-butanol, has a chemical formula of C4H10O and a molecular weight of 74.12 g/mol. It is a tertiary alcohol with a branched structure, containing a hydroxyl group attached to a carbon atom that is bonded to three other carbon atoms. On the other hand, Iso Butanol, also known as isobutyl alcohol, has a chemical formula of C4H10O and a molecular weight of 74.12 g/mol. It is a primary alcohol with a branched structure, containing a hydroxyl group attached to a carbon atom that is bonded to two other carbon atoms.
Physical Properties
2-Methylpropan-2-ol is a colorless liquid with a characteristic odor, a melting point of -51°C, and a boiling point of 82.2°C. It is soluble in water and miscible with most organic solvents. Iso Butanol is also a colorless liquid with a mild, alcohol-like odor, a melting point of -108.5°C, and a boiling point of 107.9°C. It is slightly soluble in water and miscible with organic solvents such as ether and acetone.
Uses
2-Methylpropan-2-ol is commonly used as a solvent in the production of coatings, inks, and adhesives. It is also used as a chemical intermediate in the synthesis of pharmaceuticals and agricultural chemicals. Iso Butanol is used as a solvent in the manufacturing of paints, varnishes, and lacquers. It is also used as a raw material in the production of plasticizers and esters.
Flammability
2-Methylpropan-2-ol has a flash point of 11°C and a flammability rating of 3, indicating it is a moderate fire hazard. It can form explosive mixtures with air at temperatures above its flash point. Iso Butanol has a flash point of 35°C and a flammability rating of 2, making it a slight fire hazard. It can also form explosive mixtures with air under certain conditions.
Toxicity
2-Methylpropan-2-ol is considered to be moderately toxic, with a LD50 (median lethal dose) of 2,500 mg/kg in rats. It can cause irritation to the skin, eyes, and respiratory tract upon exposure. Iso Butanol is also moderately toxic, with a LD50 of 2,600 mg/kg in rats. It can cause similar irritations to the skin, eyes, and respiratory tract.
Environmental Impact
2-Methylpropan-2-ol is biodegradable and does not persist in the environment. It has a low potential for bioaccumulation in aquatic organisms. Iso Butanol is also biodegradable and does not persist in the environment. It has a low potential for bioaccumulation in aquatic organisms as well.
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